先德科技汇集国内外生物乙醇、生物柴油等生物燃料相关标准，并研制配套标准样品供实验室检测使用

创建时间：2022-10-28 09:50

标准样品(reference material,RM) 具有一种或多种规定特性足够均匀且稳定的材料，已被确定其符合测量过程的预期用途。将标准样品定位于“对国家标准中规定的技术指标以及有关分析试验方法，需要配套标准样品才能确保其有效实施时，应当研制和使用相应的国家标准样品。

生物燃料(biofuel)泛指由生物质组成或萃取的固体、液体或气体燃料，可以替代由石油制取的汽油和柴油，是可再生能源开发利用的重要方向。生物质是指利用大气、水、土地等通过光合作用而产生的各种有机体，即一切有生命的可以生长的有机物质。它包括植物、动物和微生物，不同于石油、煤炭、核能等传统燃料，这些新兴的燃料是可再生燃料。生物质是地球上总量最丰富、分布最广泛的资源。可分为常规生物燃料和先进生物燃料。

本文汇总了目前生物乙醇、生物柴油等生物燃料国内外相关标准，并研制了配套标准样品供实验室检测使用。

ASTM D93-20 Standard Test Methods for Flash Point by Pensky-Martens Closed Cup Tester

SCOPE: These test methods cover the determination of the flash point of petroleum products in the temperature range from 40 °C to 370 °C by a manual Pensky-Martens closed-cup apparatus or an automated Pensky-Martens closed-cup apparatus, and the determination of the flash point of biodiesel in the temperature range of 60 °C to 190 °C by an automated Pensky-Martens closed cup apparatus.

ASTM D2500-17a Standard Test Method for Cloud Point of Petroleum Products and Liquid Fuels 石油产品浊点标准试验方法

SCOPE：This test method covers only petroleum products and biodiesel fuels that are transparent in layers 40 mm in thickness, and with a cloud point below 49 °C.

ASTM D4806 Standard Specification for Denatured Fuel Ethanol for Blending with Gasolines for Use as Automotive Spark-Ignition Engine Fuel

SCOPE: This specification covers nominally anhydrous denatured fuel ethanol intended to be blended with unleaded or leaded gasolines at 1 % to 15 % by volume for use as automotive spark-ignition engine fuel covered by Specification D4814 as well as other fuel applications or specifications involving ethanol. The significance of this specification is shown in Appendix X1.

ASTM D4951 Standard Test Method for Determination of Additive Elements in Lubricating Oils by Inductively Coupled Plasma Atomic Emission Spectrometry

SCOPE: This test method covers the quantitative determination of barium, boron, calcium, copper, magnesium, molybdenum, phosphorus, sulfur, and zinc in unused lubricating oils and additive packages.

ASTM5186 Standard Test Method for Determination of the Aromatic Content and Polynuclear Aromatic Content of Diesel Fuels By Supercritical Fluid Chromatography 用超临界流体色谱法测定柴油燃料中芳烃含量和多核芳烃含量的标准试验方法

ASTM D5453-19a Standard Test Method for Determination of Total Sulfur in Light Hydrocarbons, Spark Ignition Engine Fuel, Diesel Engine Fuel, and Engine Oil by Ultraviolet Fluorescence 轻质烃及发动机燃料和其他油品的总硫含量测定法(紫外荧光法)

ASTM D5501 Standard Test Method for Determination of Ethanol and Methanol Content in Fuels Containing Greater than 20% Ethanol by Gas Chromatography

ASTM D6304-20 Standard Test Method for Determination of Water in Petroleum Products, Lubricating Oils, and Additives by Coulometric Karl Fischer Titration 石油产品、润滑油和添加剂水分含量测定法

SCOPE: This test method covers the direct determination of entrained water in petroleum products and hydrocarbons using automated instrumentation. This test method also covers the indirect analysis of water thermally removed from samples and swept with dry inert gas into the Karl Fischer titration cell. Mercaptan, sulfide (S– or H2S), sulfur, and other compounds are known to interfere with this test method (see Section 6). The precision statement of this method covers the nominal range of 20 mg/kg to 25 000 mg/kg for Procedure A, 30 mg/kg to 2100 mg/kg for Procedure B, and 20 mg/kg to 360 mg/kg for Procedure C.

ASTM D6584-21 Standard Test Method for Determination of Total Monoglycerides, Total Diglycerides, Total Triglycerides, and Free and Total Glycerin in B-100 Biodiesel Methyl Esters by Gas Chromatography

SCOPE: This test method covers the quantitative determination of total monoglyceride, total diglyceride, total triglyceride, and free and total glycerin in B-100 methyl esters by gas chromatography. The range of quantitation for monoglyceride is 0.009 % to 0.77860 % by mass, for diglyceride is 0.092353 % to 0.54475 % by mass, and for triglyceride is 0.00092857 % to 1.3881 % by mass. The range of quantitation for free glycerin is 0.0005714 % to 0.019533 % by mass and for total glycerin from 0.0090714 % to 0.42767 % by mass. This procedure is not applicable to vegetable oil methyl esters obtained from lauric oils, such as coconut oil and palm kernel oil.

ASTM D6751-20a Standard Specification for Biodiesel Fuel Blend Stock (B100) for Middle Distillate Fuels

SCOPE: This specification covers biodiesel fuel blend stock, B100, in Grades S15 and S500 for use as a blend component with middle distillate fuels. This specification prescribes the required properties of diesel fuels at the time and place of delivery. The requirements stated here may be applied at other points in the production and distribution system when provided by agreement between the purchaser and the supplier. The biodiesel specified shall be mono-alkyl esters of long chain fatty acids derived from vegetable oils and animal fats. The product shall undergo chemical analysis for flash point, methanol, water and sediment, kinematic viscosity, sulfated ash, oxidation stability, sulfur, copper strip corrosion, cetane number, cloud point, acid number, carbon residue, total and free glycerin, phosphorus, reduce pressure distillation temperature, atmospheric equivalent temperature, combined calcium and magnesium, and combined sodium and magnesium.

EN228 Automotive fuels - Unleaded petrol - Requirements and test methods

SCOPE: This European Standard specifies requirements and test methods for marketed and delivered unleaded petrol. It is applicable to unleaded petrol for use in petrol engine vehicles designed to run on unleaded petrol.

EN 15721:2013 Ethanol as a blending component for petrol - Determination of higher alcohols, methanol and other impurities - Gas chromatographic method

SCOPE: This European Standard specifies a gas chromatographic method for ethanol, in which higher alcohols (propan-1-ol, butan-1-ol, butan-2-ol, 2-methylpropan-1-ol (isobutanol), 2 methylbutan 1 ol, and 3 methylbutan 1 ol) from 0,1 % up to 2,5 % (m/m), methanol from 0,1 % up to 3 % (m/m) and other impurities, in the range from 0,1 % up to 2 % (m/m) are determined. Impurities are all the compounds not attributed to the groups of higher alcohols or methanol. Due to possible interferences, the method is not applicable to denatured ethanol samples. Water, if present in the sample, is not included in this analysis, because a signal for water is not visible in the chromatogram. Therefore, if "alcohol content" is called up in a specification, water needs to be considered separately in the calculations. NOTE For the purposes of this European Standard, the term “% (m/m)” is used to represent the mass fraction (ω).

EN 12916 Petroleum products - Determination of aromatic hydrocarbon types in middle distillates - High performance liquid chromatography method with refractive index detection

SCOPE：本文件规定了测定柴油燃料、石蜡柴油燃料和石油馏分中单芳烃、双芳烃和三环以上芳烃含量的试验方法。

This document specifies a test method for the determination of the content of mono-aromatic, di-aromatic and tri+-aromatic hydrocarbons in diesel fuels, paraffinic diesel fuels and petroleum distillates.

EN14103 Fat and oil derivatives - Fatty Acid Methyl Esters (FAME) -Determination of ester and linolenic acid methyl ester Contents

SCOPE:The purpose of this document is to describe a procedure for the determination of the ester content in fatty acid methyl esters (FAME) intended for incorporation into diesel oil. It also allows determining the linolenic acid methyl ester content. It allows verifying that the ester content of FAME is greater than 90 % (m/m) and that the linolenic acid methyl ester content is between 1 % (m/m) and 15 % (m/m).

EN 14105:2020 Fat and oil derivatives - Fatty Acid Methyl Esters (FAME) - Determination of free and total glycerol and mono-, di-, triglyceride contents

本文件规定了脂肪酸甲酯（FAME）中游离甘油和残余单、双和甘油三酯含量的测定方法。然后根据所得结果计算总甘油含量。在所述条件下，游离甘油的定量限为0001%（m/m），所有甘油酯（一元、二元和三元）的定量限为0.10%（m/m）。本法适用于菜籽、向日葵、大豆、棕榈油、动物油脂及其混合物制备脂肪酸甲酯。由于不同甘油酯峰重叠，不适用于由椰子油和棕榈仁油衍生物生产或含有椰子油和棕榈仁油衍生物的脂肪酸。注1:在本文件中，术语“%（m/m）”用于表示质量分数。注2:在常见的EN 14105气相色谱条件下，角鲨烯可与α-甘油单硬脂酸盐共存。如果怀疑存在角鲨烯，可使用EN 17057区分角鲨烯和单硬脂酸甘油酯。警告-使用本文件可能涉及危险材料、操作和设备。本文件并不旨在解决与其使用相关的所有安全问题。本文件的使用者有责任在应用本标准之前采取适当措施确保人员的安全和健康，并满足相关的法律法规要求。

SCOPE:This document specifies a method to determine the free glycerol and residual mono-, di- and triglyceride contents in fatty acid methyl esters (FAME). The total glycerol content is then calculated from the obtained results. Under the conditions described, the quantification limits are 0,001 % (m/m) for free glycerol, 0,10 % (m/m) for all glycerides (mono-, di- and tri-). This method is suitable for FAME prepared from rapeseed, sunflower, soybean, palm, animal oils and fats and mixture of them. It is not suitable for FAME produced from or containing coconut and palm kernel oils derivatives because of overlapping of different glyceride peaks.

EN 14107:Fat and oil derivatives - Fatty Acid Methyl Esters (FAME) - Determination of phosphorus content by inductively coupled plasma (ICP) emission spectrometry

SCOPE:This European Standard specifies an inductively coupled plasma (ICP) emission spectrometry method for thedetermination of phosphorus content between 4 mg/kg and 20 mg/kg in Fatty Acid Methyl Esters, hereinafterreferred as FAME.This method aims to evaluate the FAME quality, in terms of transesterification by-products content such asphosphorus, whose concentration may affect the fuel behaviour.

EN14110 Fat and oil derivatives – Fatty Acid Methyl Esters – Determination of methanol content

SCOPE：specifies a method for the determination of the methanol content of fatty acid methyl esters (FAME) for use as diesel fuel and domestic heating fuel. The method is applicable to methanol contents between 0,01 % (m/m) and 0,5 % (m/m). The method is not applicable to mixtures of FAME containing other low boiling components.

EN 15779:2009：Petroleum products and fat and oil derivates - Fatty acid methyl esters (FAME) for diesel engines -Determination of polyunsaturated (≥4 double bonds) fatty acid methyl esters (PUFA) by gas chromatography

SCOPE:This European Standard specifies a method for the determination of the polyunsaturated (≥ 4 double bonds) fatty acid (PUFA) methyl esters content of fatty acid methyl ester (FAME) as a whole between 0,6 % (m/m) and 1,5 % (m/m).

The method covers the predominant four polyunsaturated fatty acid methyl esters of eicosatetraenoic acid (C 20:4 (n-6)), eicosapentaenoic acid (C 20:5 (n-3)), docosapentaenoic acid (C 22:5 (n-3), and docosahexaenoic acid (C 22:6 (n-3)).

EN 14214 Liquid petroleum products - Fatty acid methyl esters (FAME) for use in diesel engines and heating applications - Requirements and test methods

SCOPE： This European Standard specifies requirements and test methods for marketed and delivered fatty acid methyl esters (hereafter known as FAME) to be used either as fuel for diesel engines and for heating applications at 100 % concentration, or as an extender for distillate fuel for diesel engines in accordance with the requirements of EN 590 and for heating fuel. At 100 % concentration it is applicable to fuel for use in diesel engines and in heating applications designed or subsequently adapted to run on 100 % FAME.

IP 391 : 2007 PETROLEUM PRODUCTS - DETERMINATION OF AROMATIC HYDROCARBON TYPES IN MIDDLE DISTILLATES - HIGH PERFORMANCE LIQUID CHROMATOGRAPHY METHOD WITH REFRACTIVE INDEX DETECTION 生物柴油燃料中三环及三环以上芳烃检测方案(液相色谱仪)

SCOPE：本欧洲标准规定了一种测试方法，用于测定可能含有高达5%（V/V）脂肪酸甲酯（FAME）和沸点在150°C至400°C范围内的石油馏分的柴油中单芳香烃、双芳香烃和三环以上芳香烃的含量。

IP585 Fatty Acid Methyl Esters (FAMEs) in Aviation Turbine Fuel

ISO 3679:2015 Determination of flash no-flash and flash point — Rapid equilibrium closed cup method

SCOPE: ISO 3679:2015 specifies procedures for flash point tests, within the temperature range of -30 °C to 300 °C, for paints, including water-borne paints, varnishes, binders for paints and varnishes, adhesives, solvents, petroleum, and related products. The procedures are used to determine whether a product will or will not flash at a specified temperature (flash no-flash Procedure A) or the flash point of a sample (Procedure B). When used in conjunction with a flash detector, ISO 3679:2015 is also suitable to determine the flash point of fatty acid methyl esters (FAME).

ISO 12937:2000 Petroleum products — Determination of water — Coulometric Karl Fischer titration method

SCOPE:This International Standard specifies a method for the direct determination of water in petroleum products boiling below 390 °C. It covers the mass fraction range 0,003 % (m/m) to 0,100%(m/m). It is not applicable to products containing ketones or to residual fuel oils.

This European Standard specifies a test method forthe determination of the content of mono-aromatic,di-aromatic and tri+-aromatic hydrocarbons in dieselfuels that may contain fatty acid methyl esters(FAME) up to 5 % (V/V) and petroleum distillates inthe boiling range from 150 °C to 400 °C.

GB 17930 车用汽油

范围：本标准规定了车用汽油的术语和定义、产品分类、要求和试验方法、取样、标志、包装、运输和贮存、安全及标准的实施。本标准适用于点燃式发动机使用的、由石油制取或由石油制取的加有改善使用性能添加剂的车用汽油。

GB 18350-2013 变性燃料乙醇

GB 18351-2017车用乙醇汽油(E10)

GB/T 23801 中间馏分油中脂肪酸甲酯含量的测定红外光谱法

GB 35793-2018 车用乙醇汽油E85

SH/T 0606中间馏分烃类组成测定法(质谱法)

SH/T 0806

SH/T0831 生物柴油中脂肪酸甲酯及亚麻酸甲酯含量的测定气相色谱法

T/CPCIF 00XX— 20XX 生物柴油 B100

T/CPCIF 00XX— 20XX 生生物质基汽柴油添加剂中含氧组分的测定气相色谱-质谱联用法

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